Of course Daniel Craig was a) going to have a hot woman on his arm and b) look super sharp. It's total 007. Berenice Marlohe looked Bond Girl appropriate in a corseted red gown and lashings of vixen eyeliner.
One outfit down, Berenice slipped into something a little more comfortable later.
Bond's other leading lady Naomi Harris looked fab in her second choice of the night. We weren't sure about the first...
Ah, Dame Judy Dench. What a fabulous look. 007's boss opted for a chic and totally OTM pastel blue outfit with oversized tailoring and sleek lines.
Bond villain Javier Bardem took along wife Penelope Cruz who glistened in her golden L'Wren Scott gown.
Kelly Brook oozed glamour in her form-fitting sequinned dress and movie star beauty.
Stritcly Come Dancing judge Darcey Bussell popped on a red carpet ready fishtail gown for the night, perfect for a James Bond shindig.
Newlyweds Holly Valance and Nick Candy enjoyed a very posh date night. After seeing Gwyneth Paltrow and Sienna Miller rock a cape recently, we're beginning to think this is a bit of a trend...
Strictly contestant Victoria Pendleton shone in her shimmering silver floorsweeper. You get a 10 from us!
Another star to take inspiration from the carpet was Minnie Driver who looked fab in her silky draped number and matching pout.
Skyfall got the royal seal of approval when HRH Prince Charles and Camilla attended both looking very dapper indeed. Yes, that is a lot of velvet but we think Camilla more than pulls it off.
The X Factor fellas donned their best suits for a night on the red carpet. Where was our fave suit wearer Gary Barlow, though, eh?
Tulisa treated her ladies to a night out too. We cannot get over how incredible Jade Ellis looks! Bond girl material right there.